One-nanometer-thick seed layer of unilamellar nanosheets promotes oriented growth of oxide crystal films

被引:92
作者
Shibata, Tatsuo [1 ]
Fukuda, Katsutoshi [1 ]
Ebina, Yasuo [1 ]
Kogure, Toshihiro [2 ]
Sasaki, Takayoshi [1 ]
机构
[1] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton & Nanoscale Mat Ctr, Tsukuba, Ibaraki 3050044, Japan
[2] Univ Tokyo, Grad Sch Sci, Dept Earth & Planetary Sci, Bunkyo Ku, Tokyo 1130033, Japan
关键词
D O I
10.1002/adma.200701381
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Room-temperature fabrication of an ultimately thin seed layer using 2D oxide nanosheets is demonstrated. Flat nanosheets are tiled to form a highly organized monolayer with a thickness of ca. 1 nm on a glass substrate (see figure). Monolayer films of nanosheets such as Ca2Nb3O10 (2D square lattice) and MnO2 (2D hexagonal) successfully promote oriented film growth of oxide crystals such as SrTiO3 (cubic), TiO2 (tetragonal), and ZnO (hexagonal).
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页码:231 / +
页数:6
相关论文
共 37 条
[1]   METALORGANIC VAPOR-PHASE EPITAXIAL-GROWTH OF A HIGH-QUALITY GAN FILM USING AN AIN BUFFER LAYER [J].
AMANO, H ;
SAWAKI, N ;
AKASAKI, I ;
TOYODA, Y .
APPLIED PHYSICS LETTERS, 1986, 48 (05) :353-355
[2]   Chemical solution deposition of <100>-oriented SrTiO3 buffer layers on Ni substrates [J].
Dawley, JT ;
Ong, RJ ;
Clem, PG .
JOURNAL OF MATERIALS RESEARCH, 2002, 17 (07) :1678-1685
[3]   Study on exfoliation of layered perovskite-type niobates [J].
Ebina, Y ;
Sasaki, T ;
Watanabe, M .
SOLID STATE IONICS, 2002, 151 (1-4) :177-182
[4]   Layer-by-layer growth and condensation reactions of niobate and titanoniobate thin films [J].
Fang, MM ;
Kim, CH ;
Saupe, GB ;
Kim, HN ;
Waraksa, CC ;
Miwa, T ;
Fujishima, A ;
Mallouk, TE .
CHEMISTRY OF MATERIALS, 1999, 11 (06) :1526-1532
[5]   Nanoarchitecture of semiconductor titania nanosheets revealed by polarization-dependent total reflection fluorescence X-ray absorption fine structure [J].
Fukuda, K ;
Nakai, I ;
Oishi, C ;
Nomura, M ;
Harada, M ;
Ebina, Y ;
Sasaki, T .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (35) :13088-13092
[6]   Unusual crystallization behaviors of anatase nanocrystallites from a molecularly thin titania nanosheet and its stacked forms: Increase in nucleation temperature and oriented growth [J].
Fukuda, Katsutoshi ;
Ebina, Yasuo ;
Shibata, Tatsuo ;
Aizawa, Takashi ;
Nakai, Izumi ;
Sasaki, Takayoshi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (01) :202-209
[7]   Structure analysis of exfoliated unilamellar crystallites of manganese oxide nanosheets [J].
Fukuda, Katsutoshi ;
Nakai, Izumi ;
Ebina, Yasuo ;
Tanaka, Masahiko ;
Mori, Takeharu ;
Sasaki, Takayoshi .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (34) :17070-17075
[8]   High critical current density superconducting tapes by epitaxial deposition of YBa2Cu3Ox thick films on biaxially textured metals [J].
Goyal, A ;
Norton, DP ;
Budai, JD ;
Paranthaman, M ;
Specht, ED ;
Kroeger, DM ;
Christen, DK ;
He, Q ;
Saffian, B ;
List, FA ;
Lee, DF ;
Martin, PM ;
Klabunde, CE ;
Hartfield, E ;
Sikka, VK .
APPLIED PHYSICS LETTERS, 1996, 69 (12) :1795-1797
[9]   Growth of epitaxial anatase (001) and (101) films [J].
Herman, GS ;
Gao, Y .
THIN SOLID FILMS, 2001, 397 (1-2) :157-161
[10]   Orientation control of perovskite thin films on glass substrates by the application of a seed layer prepared from oxide nanosheets [J].
Kikuta, Koichi ;
Noda, Koji ;
Okumura, Shin ;
Yamaguchi, Toshiaki ;
Hirano, Shin-ichi .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2007, 42 (03) :381-387