Early (Ti, Zr)-late (Rh, Ir) heteronuclear complexes with bridging sulphido ligands

被引:11
作者
Oro, LA [1 ]
Ciriano, MA [1 ]
Pérez-Torrente, JJ [1 ]
Casado, MA [1 ]
Hernandez-Gruel, MAF [1 ]
机构
[1] Univ Zaragoza, CSIC, Fac Ciencias, ICMA,Dept Quim Inorgan, E-50009 Zaragoza, Spain
关键词
early-late; heteronuclear; rhodium; iridium; titanium; zirconium; hydroformylation;
D O I
10.1016/S1631-0748(03)00013-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report in this account on the controlled synthesis of novel d(0)-d(8) early-late heteropolynuclear diolefin and carbonyl clusters. The synthetic approach was based on additive-deprotonation reactions involving the titanium and zirconium bis-hydrosulphido complexes of formula [Cp2Ti(SH)(2)] and [(CP2Zr)-Zr-tt(SH)(2)] and appropriate rhodium and iridium diolefin and carbonyl compounds. The significant differences between the resulting early-late complexes and their structures coming from the titanium or zirconium metalloligand precursors are highlighted. The catalytic activity of some representative titanium-rhodium and zirconium-rhodium compounds towards alkene hydroformylation was explored. Interestingly, the heterotetranuclear 'CpTi(mu(3)-S)(3)Rh-3' structure was maintained as such under mild conditions.
引用
收藏
页码:47 / 57
页数:11
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