In situ UV-Vis ESR studies on electrochemically synthesized poly(p-phenylene vinylene)

被引：3

作者：

Damlin, P

Petr, A

Kvarnström, C

Dunsch, L

Ivaska, A ^{[1
]}

机构：

[1] Abo Akad Univ, Proc Chem Grp, Analyt Chem Lab, FIN-20500 Turku, Finland

[2] Inst Solid State & Mat Res, D-01069 Dresden, Germany

来源：

SYNTHETIC METALS | 2001年 / 119卷 / 1-3期

关键词：

poly(p-phenylene vinylene); electrochemical polymerization; in situ spectroelectrochemistry; ESR spectroscopy; UV-Vis spectroscopy;

D O I：

10.1016/S0379-6779(00)00610-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this work PPV films were prepared by electrochemical reduction of alpha,alpha,alpha,alpha -tetrabromo-p-xylene in dimethylformamide and tetraethylammonium tetrafluoroborate. To get more information about the mechanism behind electrochemical polymerization of PPV and its doping reaction, in situ ESR- UV-VIS measurements were made on the electrochemically synthesized conducting polymer PPV.

引用

页码：61 / 62

页数：2

共 5 条

[1] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[2] Electrochemical synthesis of poly(paraphenylene vinylene) films [J].

Damlin, P ;

Kvarnström, C ;

Ivaska, A .

ELECTROCHIMICA ACTA, 1999, 44 (12) :1919-1931

[3] INSITU ESR INVESTIGATIONS OF ELECTROCHEMICAL SYSTEMS [J].

DUNSCH, L ;

PETR, A .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1993, 97 (03) :436-439

[4] INSITU UV-VIS-SPECTROELECTROCHEMISTRY OF LIGA-STRUCTURES [J].

NEUDECK, A ;

DUNSCH, L .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1993, 97 (03) :407-411

[5] ELECTROCHEMICAL PROPERTIES OF AN ELECTROSYNTHESIZED POLY(PARA-PHENYLENE VINYLENE) FILM AND ITS APPLICATION TO A SIMPLE ELECTROCHEMICAL FABRICATION OF A POLYMER DIODE [J].

NISHIHARA, H ;

AKASAKA, M ;

TATEISHI, M ;

ARAMAKI, K .

CHEMISTRY LETTERS, 1992, (10) :2061-2064

← 1 →