Proton conducting polymer blends and hybrid organic inorganic materials

被引：56

作者：

Lassègues, JC ^{[1
]}

Grondin, J ^{[1
]}

Hernandez, M ^{[1
]}

Marée, B ^{[1
]}

机构：

[1] Univ Bordeaux 1, Lab Phys Chim Mol, UMR 5803, F-33405 Talence, France

来源：

SOLID STATE IONICS | 2001年 / 145卷 / 1-4期

关键词：

proton conductivity; polyamide; poly(vinylidenedifluoride); H3PO4; H2SO4; Raman spectroscopy;

D O I：

10.1016/S0167-2738(01)00909-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Literature results concerning proton conducting polymer electrolytes are reviewed with emphasis on acid doped polymer blends and on derived systems obtained by adding an inorganic filler or a plasticizer or both. In addition, conductivity results are provided on anhydrous polyamide/H3PO4 blends in a wide acid concentration range and on new membranes involving a fluorinated polymer, silica and H3PO4 or H2SO4 aqueous solutions. The room temperature conductivity of 10(-1) S cm(-1) reached by these membranes is discussed using in situ Raman spectroscopy measurements of the acid concentration, General trends and prospects are tentatively drawn from the available results. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：37 / 45

页数：9

共 31 条

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