Mapping molecular orientation of pentacene on patterned Au surface

被引：6

作者：

Hsu, YJ

Hu, WS

Wei, DH

Wu, YS

Yao, YT ^{[1
]}

机构：

[1] Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan

[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan

[3] Acad Sinica, Inst Chem, Taipei 115, Taiwan

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2005年 / 144卷

关键词：

pentacene; PEEM; SAMs; micro-NEXAFS;

D O I：

10.1016/j.elspec.2005.01.244

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

With a photoemission electron microscope, we investigated the orientation of pentacene films deposited on Art surface that has been patterned with self-assembled monolayers (SAMs). Organic thiols X(CH2)(n)SH - with X = -COOH or -CH3 and an aromatic thiol; served as alignment layers to control the orientation of pentacene molecules thermally deposited on top of the SAM. According to the PEEM images and near-edge X-ray absorption fine structure spectra, a SAM exposing a non-polar methyl group, a terphenyl group or a polar carboxyl group all induced perpendicular alignment of the pentacene moiety, in contrast with parallel alignment on a bare gold surface. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：401 / 404

页数：4

共 13 条

[1] Bulk and surface characterization of a dewetting thin film polymer bilayer [J].

Ade, H ;

Winesett, DA ;

Smith, AP ;

Anders, S ;

Stammler, T ;

Heske, C ;

Slep, D ;

Rafailovich, MH ;

Sokolov, J ;

Stöhr, J .

APPLIED PHYSICS LETTERS, 1998, 73 (25) :3775-3777

[2]

CHEN YY, 1997, IEEE T ELECTRON DEV, V44, P1325

[3] X-PEEM study on surface orientation of stylized and rubbed polyimides [J].

Cossy-Favre, A ;

Diaz, J ;

Liu, Y ;

Brown, HR ;

Samant, MG ;

Stohr, J ;

Hanna, AJ ;

Anders, S ;

Russell, TP .

MACROMOLECULES, 1998, 31 (15) :4957-4962

[4]

Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO

[5]

2-9

[6] Oligophenyl-based organic thin film transistors [J].

Gundlach, DJ ;

Lin, YY ;

Jackson, TN ;

Schlom, DG .

APPLIED PHYSICS LETTERS, 1997, 71 (26) :3853-3855

[7] The physical chemistry of organic field-effect transistors [J].

Katz, HE ;

Bao, Z .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (04) :671-678

[8] Investigation of charge transport in thin, doped sexithiophene crystals by conducting probe atomic force microscopy [J].

Loiacono, MJ ;

Granstrom, EL ;

Frisbie, CD .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (10) :1679-1688

[9] Observation of antiferromagnetic domains in epitaxial thin films [J].

Scholl, A ;

Stöhr, J ;

Lüning, J ;

Seo, JW ;

Fompeyrine, J ;

Siegwart, H ;

Locquet, JP ;

Nolting, F ;

Anders, S ;

Fullerton, EE ;

Scheinfein, MR ;

Padmore, HA .

SCIENCE, 2000, 287 (5455) :1014-1016

[10] Energy level alignment and two-dimensional structure of pentacene on Au(111) surfaces [J].

Schroeder, PG ;

France, CB ;

Park, JB ;

Parkinson, BA .

JOURNAL OF APPLIED PHYSICS, 2002, 91 (05) :3010-3014

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