Porphyrin-based photocatalytic lithography

被引:16
作者
Bearinger, Jane P. [1 ]
Stone, Gary [1 ]
Christian, Allen T. [2 ]
Dugan, Lawrence [1 ]
Hiddessen, Amy L. [1 ]
Wu, Kuang Jeri J. [1 ]
Wu, Ligang [1 ]
Hamilton, Julie [1 ]
Stockton, Cheryl [1 ]
Hubbell, Jeffrey A. [3 ]
机构
[1] Lawrence Livermore Natl Lab, Phys Sci Directorate, AP Div, Livermore, CA 94550 USA
[2] Monsanto Co, St Louis, MO 63167 USA
[3] Ecole Polytech Fed Lausanne, Swiss Fed Inst Technol, Inst Bioengn AAB039, Lab Regenerat Med & Pharmacobiol,Stn 15, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1021/la703992r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photocatalytic lithography couples light with photoreactive coated mask materials to pattern surface chemistry. We excite porphyrins to create radical species that photocatalytically oxidize, and thereby pattern, chemistries in the local vicinity. The technique advantageously is suited for use with a wide variety of substrates. It is fast and robust, and the wavelength of light does not limit the resolution of patterned features. We have patterned proteins and cells to demonstrate the utility of photocatalytic lithography in life science applications.
引用
收藏
页码:5179 / 5184
页数:6
相关论文
共 31 条
[1]   Polymer-based variable focal length microlens system [J].
Agarwall, M ;
Gunasekaran, RA ;
Coane, P ;
Varahramyan, K .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2004, 14 (12) :1665-1673
[2]   Chemisorbed poly(propylene sulphide)-based copolymers resist biomolecular interactions [J].
Bearinger, JP ;
Terrettaz, S ;
Michel, R ;
Tirelli, N ;
Vogel, H ;
Textor, M ;
Hubbell, JA .
NATURE MATERIALS, 2003, 2 (04) :259-264
[3]   P(AAm-co-EG) interpenetrating polymer networks grafted to oxide surfaces: Surface characterization, protein adsorption, and cell detachment studies [J].
Bearinger, JP ;
Castner, DG ;
Golledge, SL ;
Rezania, A ;
Hubchak, S ;
Healy, KE .
LANGMUIR, 1997, 13 (19) :5175-5183
[4]  
BEARINGER JP, 2005, BIOMOLECULAR PATTERN
[5]   PDMS 2D optical lens integrated with microfluidic channels: principle and characterization [J].
Camou, S ;
Fujita, H ;
Fujii, T .
LAB ON A CHIP, 2003, 3 (01) :40-45
[6]   Micropatterned surfaces for control of cell shape, position, and function [J].
Chen, CS ;
Mrksich, M ;
Huang, S ;
Whitesides, GM ;
Ingber, DE .
BIOTECHNOLOGY PROGRESS, 1998, 14 (03) :356-363
[7]   Variable-focusing microlens with microfluidic chip [J].
Chen, J ;
Wang, WS ;
Fang, J ;
Varahramyan, K .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2004, 14 (05) :675-680
[8]   Microcontact printing of macromolecules with submicrometer resolution by means of polyolefin stamps [J].
Csucs, G ;
Künzler, T ;
Feldman, K ;
Robin, F ;
Spencer, ND .
LANGMUIR, 2003, 19 (15) :6104-6109
[9]  
DOLPHIN D, 1978, PORPHYRINS PHYS CH A
[10]   Self-assembly and steric stabilization at heterogeneous, biological surfaces using adsorbing block copolymers [J].
Elbert, DL ;
Hubbell, JA .
CHEMISTRY & BIOLOGY, 1998, 5 (03) :177-183