Formation and reactivity of a cobalt(II) hydroperoxide intermediate

被引：47

作者：

Thyagarajan, S ^{[1
]}

Incarvito, CD ^{[1
]}

Rheingold, AL ^{[1
]}

Theopold, KH ^{[1
]}

机构：

[1] Univ Delaware, Dept Chem & Biochem, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b107080k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Tp(t-Bu,Me)Co-H with O-2 proceeds via a spectroscopically observable hydroperoxide whose reactivity in solution and in the solid state differ dramatically.

引用

页码：2198 / 2199

页数：2

共 41 条

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