X-ray spectroscopic study of the electronic structure of visible-light responsive N-, C- and S-doped TiO2

被引:117
作者
Chen, Xiaobo [2 ]
Glans, Per-Anders [1 ,3 ]
Qiu, Xiaofeng [2 ]
Dayal, Smita [2 ]
Jennings, Wayne D. [4 ]
Smith, Kevin E. [3 ]
Burda, Clemens [2 ]
Guo, Jinghua [1 ]
机构
[1] Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA
[2] Case Western Reserve Univ, Dept Chem, Ctr Chem Dynam & Nanomat Res, Cleveland, OH 44106 USA
[3] Boston Univ, Dept Phys, Boston, MA 02215 USA
[4] Case Western Reserve Univ, Dept Mat Sci & Engn, Cleveland, OH 44106 USA
基金
美国国家科学基金会;
关键词
electronic structure; doped TiO2; X-ray absorption; X-ray emission; X-ray photoelectron;
D O I
10.1016/j.elspec.2007.09.002
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The electronic origins of the visible-light response of N-, C- and S-doped TiO2 have been studied using X-ray absorption, X-ray emission, and X-ray photoelectron spectroscopies. New electronic states are observed in the bulk band gap, above the valence band edge of pure TiO2, which can be directly related to the visible-light absorption of the N-, C- and S-doped TiO2 materials. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:67 / 73
页数:7
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