Host-guest driven self-assembly of linear and star supramolecular polymers

被引：106

作者：

Yebeutchou, Roger M. ^{[1
,2
]}

Tancini, Francesca ^{[1
,2
]}

Demitri, Nicola ^{[3
]}

Geremia, Silvano ^{[3
]}

Mendichi, Raniero ^{[4
]}

Dalcanale, Enrico ^{[1
,2
]}

机构：

[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

[2] Univ Parma, INSTM UdR Parma, I-43100 Parma, Italy

[3] Univ Trieste, Dipartimento Sci Chim, Ctr Eccellenza Biocristallog, I-34127 Trieste, Italy

[4] CNR, Ist Studio Macromol, I-20133 Milan, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 24期

关键词：

host-guest chemistry; phosphonate cavitands; self-assembly; supramolecular chemistry; supramolecular polymers;

D O I：

10.1002/anie.200801002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Supramolecular plasticity: The remarkable host-guest properties of phosphonate cavitands have been exploited in the self-assembly of supramolecular polymers (see picture) that feature guest-triggered reversibility and template-driven conversion from linear into star-branched forms. The structurally similar but complexation-inefficient thiophosphonate cavitand acts as chain stopper to control the degree of polymerization. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4504 / 4508

页数：5

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