High-resolution spectroscopy and analysis of the ν4 band of 80SeF6

被引：3

作者：

Rotger, M

Boudon, V

Bürger, H

Willner, H

机构：

[1] Univ Bourgogne, UMR CNRS 5027, Phys Lab, F-21078 Dijon, France

[2] Univ Gesamthsch Wuppertal, D-42097 Wuppertal, Germany

[3] Gerhard Mercator Univ, FB 6, D-47048 Duisburg, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2001年 / 339卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(01)00299-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Fourier-transform spectrum of the nu (4) bending region of (SeF6)-Se-80 around 435 cm(-1) has been recorded at a temperature of 217 K with a resolution of 2.3 x 10(-3) cm(-1). This fundamental has been analyzed using the set of programs called highly spherical top data system (HTDS). Altogether 958 transitions were assigned and fitted with an rms of 0.0003 cm(-1). The effective Hamiltonian was developed up to the fourth order. Parameters and simulations are presented. The nu (4) band center is located at 435.099 cm(-1). (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：83 / 88

页数：6

共 20 条

[1]

[Anonymous], 1992, Spherical Top Spectra

[2] NEW ANALYSIS OF UPSILON 3 BAND OF CH-12 4 FROM 2 840 TO 3 167 CM-1 [J].