High-resolution spectroscopy and analysis of the ν4 bending region of SF6 near 615 cm-1

被引:27
作者
Boudon, V
Pierre, G
Bürger, H
机构
[1] Univ Bourgogne, Phys Lab, CNRS, UMR 5027, F-21078 Dijon, France
[2] Univ Gesamthsch Wuppertal, D-42097 Wuppertal, Germany
关键词
D O I
10.1006/jmsp.2000.8267
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The high-resolution Fourier transform spectrum of the nu (4) bending region of SF6 near 615 cm(-1) has been recorded at 213 K. We were able to perform a simultaneous analysis of the nu (4) and nu (4) + nu (6) - nu (6) bands of the main isotopomer, namely (SF6)-S-32. This is the first detailed analysis of a hot band for this molecule. The nu (4) band of (SF6)-S-34 was also analyzed and the Q branch of the nu (4) band of (SF6)-S-33 was identified. In both cases we used the HTDS software developed in Dijon. (C) 2001 Academic Press.
引用
收藏
页码:304 / 311
页数:8
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