Recent Developments in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes

被引：128

作者：

Hintermann, Lukas ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

来源：

C-X BOND FORMATION | 2010年 / 31卷

关键词：

Alkenes; Alkynes; Catalysis; Heterofunctionalization; Oxygen nucleophiles; ANTI-MARKOVNIKOV HYDRATION; FRIEDEL-CRAFTS ALKYLATION; HETERO-MICHAEL ADDITION; WOOL-PALLADIUM COMPLEX; CU(I)-CATALYZED INTRAMOLECULAR CYCLIZATION; PLATINUM(III) DIMERIC COMPLEX; BIS-HOMOPROPARGYLIC ALCOHOLS; VINYL INTERCHANGE REACTION; ARYL ALLYL ETHERS; O-H BONDS;

D O I：

10.1007/978-3-642-12073-2_6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Progress in the field of metal-catalyzed redox-neutral additions of oxygen nucleophiles (water, alcohols, carboxylic acids, and others) to alkenes, alkynes, and allenes between 2001 and 2009 is critically reviewed. Major advances in reaction chemistry include development of chiral Lewis acid catalyzed asymmetric oxa-Michael additions and Lewis-acid catalyzed hydro-alkoxylations of nonactivated olefins, as well as further development of Markovnikov-selective cationic gold complex-catalyzed additions of alcohols or water to alkynes and allenes.

引用

页码：123 / 155

页数：33

共 194 条

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