Ligand substitution reactions at inorganic centers

被引:294
作者
Richens, DT [1 ]
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
D O I
10.1021/cr030705u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This review on ligand substitution reactions at inorganic centers focuses on nonsymmetrical substitution processes dealing with complex-formation reactions. The role of solvent exchange reactions is reviewed followed by a systematic survey of ligand substitution reactions on four, five-, six-, seven-, eight-, and nine-coordinate metal centers. The influence of labilization effects caused by hydroxyl ligands, metal-carbon bonds, terminal and bridged oxo and nitride ligands, and the behavior of polynuclear clusters is also highlighted.
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页码:1961 / 2002
页数:42
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