Ligand substitution reactions at inorganic centers

被引：294

作者：

Richens, DT ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL REVIEWS | 2005年 / 105卷 / 06期

关键词：

D O I：

10.1021/cr030705u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review on ligand substitution reactions at inorganic centers focuses on nonsymmetrical substitution processes dealing with complex-formation reactions. The role of solvent exchange reactions is reviewed followed by a systematic survey of ligand substitution reactions on four, five-, six-, seven-, eight-, and nine-coordinate metal centers. The influence of labilization effects caused by hydroxyl ligands, metal-carbon bonds, terminal and bridged oxo and nitride ligands, and the behavior of polynuclear clusters is also highlighted.

引用

页码：1961 / 2002

页数：42

共 340 条

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