Upper-rim functionalization of calix[4]arene by chloro(isocyanide)gold(I) groups: An entry polymetallic architecture

被引：24

作者：

Gagnon, J ^{[1
]}

Drouin, M ^{[1
]}

Harvey, PD ^{[1
]}

机构：

[1] Univ Sherbrooke, Dept Chim, Sherbrooke, PQ J1K 2R1, Canada

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 23期

关键词：

D O I：

10.1021/ic010640i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new upper-rim derivatized mono- and tetraisocyanotetra-n-propoxycalix[4]arene ligands and their mono- and tetragold(I) complexes have been synthesized from the monobromotetra-n-propoxycalix[4]arene materials, respectively, in reasonable overall yields. Room-temperature UV-vis and luminescence data indicate that the lowest energy excited states are intraligand π-π* states and that no strong Au··· Au interaction is present in the tetragold complex.

引用

页码：6052 / 6056

页数：5

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