Self-assembly and nanostructure formation of multi-functional organic π-donors

被引：54

作者：

Iyoda, Masahiko ^{[1
]}

Hasegawa, Masashi ^{[1
]}

Enozawa, Hideo ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Sci & Engn, Dept Chem, Tokyo, Japan

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 12期

关键词：

ELECTRON-TRANSFER OXIDATION; SHAPE-PERSISTENT; TETRATHIAFULVALENE DERIVATIVES; SUPRAMOLECULAR CHEMISTRY; RADICAL-CATIONS; BUILDING-BLOCKS; CHARGE-TRANSFER; HYDROGEN-BONDS; MIXED-VALENCE; MACROCYCLES;

D O I：

10.1246/cl.2007.1402

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of tetrathiafulvalenes, their conjugated oligomers, and giant macrocyclic oligothiophenes in solution leads to important solvatochromic, thermochromic, electrochromic, and switching properties. Furthermore, based on the self-assembly in solution. various nanostructures can be constructed in the solid state to produce nanowires, nanoparticles, nanotubes, tapes, ribbons, and microcrystals. This article highlights the self-aggregation of organic pi-donors in solution and the formation of nanostructures from these pi-donors in the solid state.

引用

页码：1402 / 1407

页数：6

共 96 条

[41] Synthesis of nonaphenylenes and dodecaphenylenes using electron-transfer oxidation of Lipshutz cuprate intermediates [J].