Valence-tautomeric metal-organic nanoparticles

被引：125

作者：

Imaz, Inhar ^{[2
]}

Maspoch, Daniel ^{[2
]}

Rodriguez-Blanco, Clara ^{[3
]}

Perez-Falcon, Jose Manuel ^{[1
]}

Campo, Javier ^{[3
]}

Ruiz-Molina, Daniel ^{[1
]}

机构：

[1] Ctr Invest Nanociencia Nanotechnol, Inst Ciencias Mat Barcelona, Bellaterra 08193, Spain

[2] Inst Catala Nanotechnol, Bellaterra 08193, Spain

[3] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 10期

关键词：

cobalt; coordination polymers; magnetic properties; nanostructures; tautomerism;

D O I：

10.1002/anie.200705263

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic nanoparticles (see SEM image) showing valence-tautomeric behavior have been obtained by a versatile approach involving precipitation and coordination polymerization. They undergo reversible temperature-dependent interconversion between low- and high-spin forms, as revealed by plotting the magnetic moment χ as a function of temperature. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1857 / 1860

页数：4

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