Chemical vapor deposition of gallium selenide and indium selenide nanoparticles

被引:48
作者
Stoll, SL [1 ]
Gillan, EG [1 ]
Barron, AR [1 ]
机构
[1] RICE UNIV,DEPT MECH ENGN & MAT SCI,HOUSTON,TX 77005
关键词
D O I
10.1002/cvde.19960020506
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Communication: Nanometer-sized structures can exhibit quite different properties from those of their macroscopic forms. In this paper it is reported that, under suitable conditions. well-defined nanoparticles of InSe and GaSe may be obtained from the vapor phase thermolysis of heterocubane molecules. For example, InSe grown from [(EtMe(2)C)InSe](4) consists of spheres with a mean diameter of 88 nm (standard deviation s.d. = 30 nm), while GaSe grown front [((t)Bu)GaSe](4) produces pseudo-spherical nanoparticles with a mean diameter of 42 nm (s.d. = 13 nm). Possible controlling mechanisms are discussed.
引用
收藏
页码:182 / &
页数:4
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