A polyaniline-intercalated layered manganese oxide nanocomposite prepared by an inorganic/organic interface reaction and its high electrochemical performance for Li storage

被引：122

作者：

Wang, Yong-Gang ^{[1
,2
]}

Wu, Wen ^{[1
,2
]}

Cheng, Liang ^{[1
,2
]}

He, Ping ^{[1
,2
]}

Wang, Cong-Xiao ^{[1
,2
]}

Xia, Yong-Yao ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 11期

关键词：

D O I：

10.1002/adma.200701708

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyaniline is intercalated into layered manganese oxide in situ, at an aqueous/organic interface. The prepared polymer intercalated manganese oxide has several novel characteristics - a swelled layered structure, a uniform mesoporous structure, a typical nanosize, and a high surface area, resulting in a high electrochemical performance for Li storage.

引用

收藏

页码：2166 / +

页数：6

相关论文

共 29 条

[1] Preparation of thin films of a layered titanate by the exfoliation of CsxTi(2-x/4)□(x/4)O4 [J].

Abe, R ;

Shinohara, K ;

Tanaka, A ;

Hara, M ;

Kondo, JN ;

Domen, K .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :329-333

[2] High-power alkaline Zn-MuO2 batteries using γ-MnO2 nanowires/nanotubes and electrolytic zinc powder [J].

Cheng, FY ;

Chen, J ;

Gou, XL ;

Shen, PW .

ADVANCED MATERIALS, 2005, 17 (22) :2753-+

[3]

FEN Q, 1995, CHEM MATER, V7, P1722

[4] Structure analysis of exfoliated unilamellar crystallites of manganese oxide nanosheets [J].

Fukuda, Katsutoshi ;

Nakai, Izumi ;

Ebina, Yasuo ;

Tanaka, Masahiko ;

Mori, Takeharu ;

Sasaki, Takayoshi .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (34) :17070-17075

[5] Preparation of nanometer-sized manganese oxides by intercalation of organic ammonium ions in synthetic birnessite OL-1 [J].

Gao, QM ;

Giraldo, O ;

Tong, W ;

Suib, SL .

CHEMISTRY OF MATERIALS, 2001, 13 (03) :778-786

[6] Layered Oxysulfides Sr2MnO2Cu2m-0.5Sm+1 (m=1, 2, and 3) as Insertion Hosts for Li ion batteries [J].

Indris, Sylvio ;

Cabana, Jordi ;

Rutt, Oliver J. ;

Clarke, Simon J. ;

Grey, Clare P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (41) :13354-13355

[7] Synthesis and structural study on MnO2 nanosheet material by X-ray absorption spectroscopic technique [J].

Kadoma, Y ;

Uchimoto, Y ;

Wakihara, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (01) :174-177

[8] Photoinduced energy and electron transfer reactions in lamellar polyanion/polycation thin films: Toward an inorganic "leaf" [J].

Kaschak, DM ;

Lean, JT ;

Waraksa, CC ;

Saupe, GB ;

Usami, H ;

Mallouk, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) :3435-3445

[9] Photoinduced charge separation in multilayer thin films grown by sequential adsorption of polyelectrolytes [J].

Keller, SW ;

Johnson, SA ;

Brigham, ES ;

Yonemoto, EH ;

Mallouk, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (51) :12879-12880

[10] Concurrent polymerization and insertion of aniline in molybdenum trioxide: Formation and properties of a [poly(aniline)]0.24MoO3 nanocomposite [J].

Kerr, TA ;

Wu, H ;

Nazar, LF .

CHEMISTRY OF MATERIALS, 1996, 8 (08) :2005-2015