Rhodium-Catalyzed Direct Addition of Aryl C-H Bonds to N-Sulfonyl Aldimines

被引：237

作者：

Li, Yang ^{[1
,2
,3
]}

Li, Bi-Jie ^{[1
,2
,3
]}

Wang, Wen-Hua ^{[1
,2
,3
]}

Huang, Wei-Ping ^{[1
,2
,3
]}

Zhang, Xi-Sha ^{[1
,2
,3
]}

Chen, Kang ^{[1
,2
,3
]}

Shi, Zhang-Jie ^{[1
,2
,3
,4
]}

机构：

[1] Peking Univ, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[3] Peking Univ, Green Chem Ctr, Beijing 100871, Peoples R China

[4] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 09期

关键词：

addition reactions; catalysis; C-H activation; rhodium; sulfonyl aldimines; CROSS-COUPLING REACTIONS; ARYLBORONIC ACIDS; DIRECT ARYLATION; ASYMMETRIC ARYLATION; ACTIVATION; FUNCTIONALIZATION; PALLADIUM; RH; HETEROCYCLES; ALDEHYDES;

D O I：

10.1002/anie.201007464

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mild mannered reaction: An ideal addition of "inert" aryl Ci-H bonds to Cï£N groups has been achieved in the absence of any additives and without any undesirable by-products (see scheme). The reaction can be carried out under mild conditions without the requirement of special techniques. Cp*=pentamethylcyclopentadienyl. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2115 / 2119

页数：5

共 96 条

[71] Stereoselective "electrophilic" cyclometalation of planar-prochiral (η6-arene)tricarbonylchromium complexes with asymmetric metal centers:: pseudo-T-4 [Cp*RhCl2]2 and [Cp*IrCl2]2 [J].