Rhodium-Catalyzed Direct Addition of Aryl C-H Bonds to N-Sulfonyl Aldimines

被引：237

作者：

Li, Yang ^{[1
,2
,3
]}

Li, Bi-Jie ^{[1
,2
,3
]}

Wang, Wen-Hua ^{[1
,2
,3
]}

Huang, Wei-Ping ^{[1
,2
,3
]}

Zhang, Xi-Sha ^{[1
,2
,3
]}

Chen, Kang ^{[1
,2
,3
]}

Shi, Zhang-Jie ^{[1
,2
,3
,4
]}

机构：

[1] Peking Univ, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[3] Peking Univ, Green Chem Ctr, Beijing 100871, Peoples R China

[4] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 09期

关键词：

addition reactions; catalysis; C-H activation; rhodium; sulfonyl aldimines; CROSS-COUPLING REACTIONS; ARYLBORONIC ACIDS; DIRECT ARYLATION; ASYMMETRIC ARYLATION; ACTIVATION; FUNCTIONALIZATION; PALLADIUM; RH; HETEROCYCLES; ALDEHYDES;

D O I：

10.1002/anie.201007464

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mild mannered reaction: An ideal addition of "inert" aryl Ci-H bonds to Cï£N groups has been achieved in the absence of any additives and without any undesirable by-products (see scheme). The reaction can be carried out under mild conditions without the requirement of special techniques. Cp*=pentamethylcyclopentadienyl. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2115 / 2119

页数：5

共 96 条

[41] N-BOC-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines [J].

Kuriyama, M ;

Soeta, T ;

Hao, XY ;

Chen, O ;

Tomioka, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (26) :8128-8129

[42] Understanding and exploiting C-H bond activation [J].

Labinger, JA ;

Bercaw, JE .

NATURE, 2002, 417 (6888) :507-514

[43] Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation [J].

Lewis, Jared C. ;

Bergman, Robert G. ;

Ellman, Jonathan A. .

ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (08) :1013-1025

[44]

Li B.-J., 2008, ANGEW CHEM, V120, P10278

[45] Interval recursive least-squares filtering with applications to video target tracking [J].

Li, Baohua ;

Li, Changchun ;

Si, Jennie ;

Abousleman, Glen P. .

OPTICAL ENGINEERING, 2008, 47 (10)

[46] Recent advances in direct arylation via palladium-catalyzed aromatic C-H activation [J].

Li, Bi-Jie ;

Yang, Shang-Dong ;

Shi, Zhang-Jie .

SYNLETT, 2008, (07) :949-957

[47] Ir-catalyzed highly selective addition of pyridyl C-H bonds to aldehydes promoted by triethylsilane [J].

Li, Bi-Jie ;

Shi, Zhang-Jie .

CHEMICAL SCIENCE, 2011, 2 (03) :488-493

[48] An efficient low-temperature route to polycyclic isoquinoline salt synthesis via C-H activation with [Cp☆MCl2]2 (M = Rh, Ir) [J].

Li, Ling ;

Brennessel, William W. ;

Jones, William D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (37) :12414-12419

[49] C-H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2 (M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism [J].

Li, Ling ;

Brennessel, William W. ;

Jones, William D. .

ORGANOMETALLICS, 2009, 28 (12) :3492-3500

[50] Mechanism of Ni-Catalyzed Selective C-O Bond Activation in Cross-Coupling of Aryl Esters [J].

Li, Zhe ;

Zhang, Song-Lin ;

Fu, Yao ;

Guo, Qing-Xiang ;

Liu, Lei .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8815-8823

← 1 2 3 4 5 6 7 8 9 10 →