N-BOC-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines

被引：207

作者：

Kuriyama, M ^{[1
]}

Soeta, T ^{[1
]}

Hao, XY ^{[1
]}

Chen, O ^{[1
]}

Tomioka, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 26期

关键词：

D O I：

10.1021/ja0475398

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A catalytic asymmetric arylation of sterically tuned imines with arylboroxines was developed by using N-Boc-L-valine-connected amidomonophosphane rhodium(I) catalyst in n-PrOH. The TMS group used for the steric tuning of imines is convertible to other functionalities that are applicable as a key foothold for the carbon-carbon bond-forming coupling reactions. Copyright © 2004 American Chemical Society.

引用

页码：8128 / 8129

页数：2

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