Pore Space Partition and Charge Separation in Cage-within-Cage Indium Organic Frameworks with High CO2 Uptake

被引：333

作者：

Zheng, Shou-Tian ^{[2
]}

Bu, Julia T. ^{[1
,3
]}

Li, Yufei ^{[2
]}

Wu, Tao ^{[1
]}

Zuo, Fan ^{[1
]}

Feng, Pingyun ^{[1
]}

Bu, Xianhui ^{[2
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

[3] JW N High Sch, Riverside, CA USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 48期

基金：

美国国家科学基金会;

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS; POROUS COORDINATION POLYMER; HIGH H-2 ADSORPTION; HYDROGEN STORAGE; BUILDING-BLOCKS; SURFACE; SIMULATION; ACETYLENE; POROSITY; SERIES;

D O I：

10.1021/ja106903p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The integration of negatively charged single-metal building blocks {In(CO2)(4)} and positively charged trimeric clusters {ln(3)O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.

引用

页码：17062 / 17064

页数：3

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