A General Rhodium-Catalyzed Cyanation of Aryl and Alkenyl Boronic Acids

被引：203

作者：

Anbarasan, Pazhamalai ^{[1
]}

Neumann, Helfried ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 02期

关键词：

benzonitriles; boronic acids; cyanation; homogeneous catalysis; rhodium; ARYLBORONIC ACIDS; PALLADIUM(II)-CATALYZED ADDITION; POTASSIUM HEXACYANOFERRATE(II); CONVENIENT PROCEDURE; EFFICIENT SYNTHESIS; BROMIDES; HALIDES; ALKYNES; SYSTEM; KETONES;

D O I：

10.1002/anie.201006044

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Give me a cyanide: N-cyano-N-phenyl-p-methylbenzenesulfonamide as a cyanation reagent allows the synthesis of aryl(alkenyl) nitriles in good yield under mild conditions (see scheme; cod=cycloocta-1,5-diene). Combination of the procedure with the direct borylation of arenes and hydroboration of alkynes leads to the straightforward synthesis of various nitriles. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：519 / 522

页数：4

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