High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites

被引：411

作者：

Bae, Youn-Sang ^{[2
]}

Lee, Chang Yeon ^{[1
]}

Kim, Ki Chul ^{[2
]}

Farha, Omar K. ^{[1
]}

Nickias, Peter ^{[3
]}

Hupp, Joseph T. ^{[1
]}

Nguyen, SonBinh T. ^{[1
]}

Snurr, Randall Q. ^{[2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[3] Dow Chem Co USA, Core R&D, Midland, MI 48674 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 08期

关键词：

adsorption; metal-organic frameworks; open metal sites; propane; propene; HYDROGEN STORAGE; CARBON-DIOXIDE; MOLECULAR SIMULATION; KINETIC SEPARATION; GAS-ADSORPTION; SURFACE-AREA; CO2; PROPANE; CH4; TEMPERATURE;

D O I：

10.1002/anie.201107534

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1857 / 1860

页数：4

共 52 条

[1] Storage and separation of CO2 and CH4 in silicalite, C168 schwarzite, and IRMOF-1:: A comparative study from monte carlo simulation
Babarao, Ravichandar
Hu, Zhongqiao
Jiang, Jianwen
Chempath, Shaji
Sandler, Stanley I.
[J]. LANGMUIR, 2007, 23 (02) : 659 - 666
[2] Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane
Bae, Youn-Sang
Farha, Omar K.
Spokoyny, Alexander M.
Mirkin, Chad A.
Hupp, Joseph T.
Snurr, Randall Q.
[J]. CHEMICAL COMMUNICATIONS, 2008, (35) : 4135 - 4137
[3] Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks
Bae, Youn-Sang
Mulfort, Karen L.
Frost, Houston
Ryan, Patrick
Punnathanam, Sudeep
Broadbelt, Linda J.
Hupp, Joseph T.
Snurr, Randall Q.
[J]. LANGMUIR, 2008, 24 (16) : 8592 - 8598
[4] Separation of gas mixtures using Co(II) carborane-based porous coordination polymers
Bae, Youn-Sang
Spokoyny, Alexander M.
Farha, Omar K.
Snurr, Randall Q.
Hupp, Joseph T.
Mirkin, Chad A.
[J]. CHEMICAL COMMUNICATIONS, 2010, 46 (20) : 3478 - 3480
[5] Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
Britt, David
Furukawa, Hiroyasu
Wang, Bo
Glover, T. Grant
Yaghi, Omar M.
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) : 20637 - 20640
[6] Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores
Caskey, Stephen R.
Wong-Foy, Antek G.
Matzger, Adam J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) : 10870 - +
[7] Adsorption and separation of hydrogen isotopes in carbon nanotubes: Multicomponent grand canonical Monte Carlo simulations
Challa, SR
Sholl, DS
Johnson, JK
[J]. JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (02) : 814 - 824
[8] Chen B., 2005, ANGEW CHEM, V117, P4823, DOI DOI 10.1002/ange.200462787
[9] High H2 adsorption in a microporous metal-organic framework with open metal sites
Chen, BL
Ockwig, NW
Millward, AR
Contreras, DS
Yaghi, OM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) : 4745 - 4749
[10] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
Chui, SSY
Lo, SMF
Charmant, JPH
Orpen, AG
Williams, ID
[J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150

← 1 2 3 4 5 6 →