The invention of radical reactions .37. A convenient radical synthesis of dialkyl diselenides from carboxylic acids.

被引：18

作者：

Barton, DHR

Fontana, G

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON | 1996年 / 52卷 / 34期

关键词：

D O I：

10.1016/0040-4020(96)00665-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and convenient synthesis of dialkyl diselenides from carboxylic acids by Barton PTOC ester based radical chemistry is described. This method was especially successful when O-cholestan-3 beta-yl-2,2,2-tricholoroselenoacetate and O-neopentyl selenobenzoate were used as radical traps. Copyright (C) Elsevier Science Ltd

引用

收藏

页码：11163 / 11176

页数：14

相关论文

共 55 条

[1]

Backer HJ, 1942, RECL TRAV CHIM PAY-B, V61, P802

[2]

BAGNALL KW, 1973, COMPREHENSIVE INORGA, P940

[3]

Barton D. H. R., 1990, Aldrichimica Acta, V23, P3

[4] THE INVENTION OF RADICAL REACTIONS .33. HOMOLOGATION REACTIONS OF CARBOXYLIC-ACIDS BY RADICAL-CHAIN CHEMISTRY [J].

BARTON, DHR ;

CHERN, CY ;

JASZBERENYI, JC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1995, 48 (02) :407-425

[5] ELEMENTAL WHITE PHOSPHORUS AS A RADICAL TRAP - A NEW AND GENERAL-ROUTE TO PHOSPHONIC-ACIDS [J].

BARTON, DHR ;

ZHU, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) :2071-2072

[6] THE REACTION OF CARBON RADICALS WITH SULFUR - A CONVENIENT SYNTHESIS OF THIOLS FROM CARBOXYLIC-ACIDS [J].

BARTON, DHR ;

CASTAGNINO, E ;

JASZBERENYI, JC .

TETRAHEDRON LETTERS, 1994, 35 (33) :6057-6060

[7] The invention of radical reactions .35. A novel radical fission reaction of N-sulfonylthioxocarbamates. [J].

Barton, DHR ;

Fontana, G ;

Yang, Y .

TETRAHEDRON, 1996, 52 (08) :2705-2716

[8] THE INVENTION OF RADICAL REACTIONS .18. A CONVENIENT SOLUTION TO THE 1-CARBON PROBLEM (R-CO2H-](R-CO2H)-C-13) [J].

BARTON, DHR ;

OZBALIK, N ;

VACHER, B .

TETRAHEDRON, 1988, 44 (12) :3501-3512

[9] The invention of radical reactions .36. Synthetic studies related to 3-deoxy-D-manno-2-octulosonic acid (KDO) [J].

Barton, DHR ;

Jaszberenyi, JC ;

Liu, WS ;

Shinada, T .

TETRAHEDRON, 1996, 52 (08) :2717-2726

[10] NEW METHOD FOR DEOXYGENATION OF SECONDARY ALCOHOLS [J].

BARTON, DHR ;

MCCOMBIE, SW .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (16) :1574-1585

← 1 2 3 4 5 6 →