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LiAlH4 promoted reductive deoxygenation of hydroxybenzyl alcohols via benzoquinone methide intermediates.

被引：20
作者：
Baik, W [1 ]
Lee, HJ
Koo, S
Kim, BH
机构：
[1] Myong Ji Univ, Dept Chem, Yong In 449728, Kyung Ki Do, South Korea
[2] Kwangwoon Univ, Dept Chem, Seoul, South Korea
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 44期
关键词：
D O I：
10.1016/S0040-4039(98)01803-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Primary and secondary hydroxybenzyl alcohols react with LiAlH4 in chlorobenzene to give the corresponding alkylphenols. The reaction proceeds through the formation of benzoquinone methide as an intermediate. An example of [4+2] cycloaddition of benzoquinone methide is also reported. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码：8125 / 8128
页数：4
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