Reactivity of a secondary phosphine platinum(II) complex with [Pt(norbornene)3] and PPh3.: Synthesis of new single phosphido-bridged derivatives of platinum(I) and phosphido-bridged platinum(II) hydrides

被引：51

作者：

Alonso, E

Forniés, J ^{[1
]}

Fortuño, C

Martín, A

Orpen, AG

机构：

[1] Univ Zaragoza, CSIC, Dept Quim Inorgan, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

[3] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 05期

关键词：

D O I：

10.1021/om0007973

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between cis-[Pt(C6F5)(2)(PPh2H)(2)], [Pt(norbornene)(3)], and PPh3 (1:1:1) results in the formation of the Pt(II) derivatives [(C6F5)(2)Pt(mu -PPh2)(mu -H)Pt(PPh2H)(PPh3)] (1) and [{(C6F5)(PPh3)Pt(mu -PPh2)(mu -H)}(2)Pt] (2). For the molar ratio 1:1:2 the reaction proceeds with formation of the Pt(I) derivative [(C6F5)(PPh3)Pt(mu -PPh2)Pt(PPh3)(2)] (8) and the Pt(II) derivatives [(C6F5)(2)Pt(mu -PPh2)(mu -H)Pt(PPh3)(2)] (4) and [(C6F5)(PPh3)Pt(mu -PPh2)(2)Pt(H)(PPh3)] (5). The structures of complexes 2, 3, and 5 have been established by X-ray diffraction. Spectroscopic (IR and NMR) data are also given.

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页码：850 / 859

页数：10

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