Preparation of Hybrid Latex Particles and Core-Shell Particles Through the Use of Controlled Radical Polymerization Techniques in Aqueous Media

被引:57
作者
Charleux, Bernadette [1 ]
D'Agosto, Franck [1 ]
Delaittre, Guillaume [2 ]
机构
[1] Univ Lyon 1, Lab Chim Catalyse Polymores & Procedes C2P2, CNRS UMR 5265, CPE Lyon, F-69616 Villeurbanne, France
[2] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 ED Nijmegen, Netherlands
来源
HYBRID LATEX PARTICLES: PREPARATION WITH (MINI) EMULSION POLYMERIZATION | 2010年 / 233卷
关键词
Controlled/living radical polymerization; Core shell particle; Dispersion polymerization; Emulsion polymerization; Grafting from; Hybrid; Miniemulsion polymerization; Nanogel; Nanoparticle; INITIO EMULSION POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; WATER-SOLUBLE ALKOXYAMINE; N-BUTYL ACRYLATE; AMPHIPHILIC DIBLOCK COPOLYMER; TRANSFER RAFT POLYMERIZATION; BLOCK-COPOLYMER; IN-SITU; POLYSTYRENE-LATEX; DISPERSION POLYMERIZATION;
D O I
10.1007/12_2010_64
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of hybrid and core shell nanoparticles using controlled/living radical polymerization in aqueous dispersed systems is reviewed. The processes involve emulsion, miniemulsion, and dispersion polymerizations as well as grafting techniques, with the aim of producing submicrometric latex particles with well-defined morphologies that might not be accessible via classical radical polymerization. Those morphologies include organic/inorganic hybrids, nanostructured particles, (nano)capsules, and particles with a hydrophobic core and hydrophilic shell.
引用
收藏
页码:125 / 183
页数:59
相关论文
共 172 条
[1]  
Advincula R. C., 2004, Polymer Brushes: Synthesis, Characterization, Applications
[2]   Nanostructured Polymer Composite Nanoparticles Synthesized in a Single Step via Simultaneous ROMP and ATRP Under Microemulsion Conditions [J].
Airaud, Cedric ;
Ibarboure, Emmanuel ;
Gaillard, Cedric ;
Heroguez, Valerie .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (16) :4014-4027
[3]   Bicompartmentalized polymer particles by tandem ROMP and ATRP in miniemulsion [J].
Airaud, Cedrie ;
Heroguez, Valrie ;
Gnanou, Yves .
MACROMOLECULES, 2008, 41 (09) :3015-3022
[4]   Interfacial living radical copolymerization of oil-and water-soluble comonomers to form composite polymer capsules [J].
Ali, MM ;
Stöver, HDH .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (01) :156-171
[5]   Polymeric capsules prepared by in situ synthesis and cross-linking of amphiphilic copolymer by atom transfer radical polymerization [J].
Ali, MM ;
Stöver, HDH .
MACROMOLECULES, 2003, 36 (06) :1793-1801
[6]   Polymer Encapsulated Gibbsite Nanoparticles: Efficient Preparation of Anisotropic Composite Latex Particles by RAFT-Based Starved Feed Emulsion Polymerization [J].
Ali, Syed Imran ;
Heuts, Johan P. A. ;
Hawkett, Brian S. ;
van Herk, Alex M. .
LANGMUIR, 2009, 25 (18) :10523-10533
[7]   Facile RAFT precipitation polymerization for the microwave-assisted synthesis of well-defined, double hydrophilic block copolymers and nanostructured hydrogels [J].
An, Zesheng ;
Shi, Qihui ;
Tang, Wei ;
Tsung, Chia-Kuang ;
Hawker, Craig J. ;
Stucky, Galen D. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (46) :14493-14499
[8]   Polyreactions in miniemulsions [J].
Antonietti, M ;
Landfester, K .
PROGRESS IN POLYMER SCIENCE, 2002, 27 (04) :689-757
[9]   Miniemulsion polymerization [J].
Asua, JM .
PROGRESS IN POLYMER SCIENCE, 2002, 27 (07) :1283-1346
[10]   Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization. I. The current situation [J].
Barner-Kowollik, Christopher ;
Buback, Michael ;
Charleux, Bernadette ;
Coote, Michelle L. ;
Drache, Marco ;
Fukuda, Takeshi ;
Goto, Atsushi ;
Klumperman, Bert ;
Lowe, Andrew B. ;
Mcleary, James B. ;
Moad, Graeme ;
Monteiro, Michael J. ;
Sanderson, Ronald D. ;
Tonge, Matthew P. ;
Vana, Philipp .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (20) :5809-5831