Bicompartmentalized polymer particles by tandem ROMP and ATRP in miniemulsion

被引：28

作者：

Airaud, Cedrie ^{[1
]}

Heroguez, Valrie ^{[1
]}

Gnanou, Yves ^{[1
]}

机构：

[1] Univ Bordeaux 1, UMR CNRS ENSCPB, Lab Chim Polymeres Organ, F-33607 Pessac, France

来源：

MACROMOLECULES | 2008年 / 41卷 / 09期

关键词：

D O I：

10.1021/ma702682s

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This Study describes an original approach to prepare biphasic particles by simultaneous ring-opening metathesis polymerization (ROMP) of norbornene and atom-transfer radical polymerization (ATRP) of methyl methacrylate under miniemulsion conditions. A single water-soluble ruthenium macrocatalyst was used to initiate ROMP and mediate ATRP. All situations led to high conversions, and well-distributed particles containing two incompatible homopolymers grown under controlled conditions could indeed be prepared.

引用

页码：3015 / 3022

页数：8

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