New types of catalytic oxidations in organic synthesis

被引：30

作者：

Murahashi, SI ^{[1
]}

Komiya, N ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 560, Japan

来源：

CATALYSIS TODAY | 1998年 / 41卷 / 04期

关键词：

D O I：

10.1016/S0920-5861(98)00024-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Simulation of the enzymatic function of cytochrome P-450 with transition metal complex catalysts has resulted in finding biomimetic and catalytic oxidations of amines, amides, beta-lactams, alcohols, phenols and hydrocarbons by using ruthenium catalyst and peroxide. Further study revealed that the catalytic formation of peracids in situ from aldehydes and molecular oxygen enables the aerobic oxidation of beta-lactams, alcohols, alkanes and ketones in the presence of metal catalyst under mild conditions. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：339 / 349

页数：11

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