The Rh, Co, Ru metal-catalyzed hydroformylation of hex-l-ene using triphenylphosphine, triphenylarsine and triphenylantimony as ligands

被引：24

作者：

Srivastava, VK ^{[1
]}

Shukla, RS ^{[1
]}

Bajaj, HC ^{[1
]}

Jasra, RV ^{[1
]}

机构：

[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Discipline, Bhavnagar 364002, Gujarat, India

来源：

APPLIED CATALYSIS A-GENERAL | 2005年 / 282卷 / 1-2期

关键词：

hex-l-ene; ligands; hydroformylation; sigma-donor/pi-acceptor ratio; transition metals;

D O I：

10.1016/j.apcata.2004.11.040

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A comparative study has been made of transition metal-catalyzed hydroformylation of hex-1-ene using rhodium, cobalt and ruthenium complexes of triphenylphosphine, triphenylarsine and triphenylantimony as catalysts. The catalytic activities of the ligands with the studied metals vary in the order: Ph3P approximate to Ph3As > Ph3Sb under employed reaction conditions. The hydroformylation activity of M/AsPh3. Systems was comparable and even higher under some experimental conditions than that of M/PPh3 systems. The only significant difference, which makes M/PPh3 systems better than M/AsPh3 systems, was the higher normal/iso (n/iso) ratio of heptanal for M/PPh3 Systems. (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：31 / 38

页数：8

共 34 条

[1] High-pressure effects in the homogeneously catalyzed hydroformylation of olefins [J].

Albers, J ;

Dinjus, E ;

Pitter, S ;

Walter, O .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 219 (01) :41-46

[2] COMMENTS ON THE SYNTHESIS OF TRISULFONATED TRIPHENYLPHOSPHINE - REACTION MONITORING BY NMR-SPECTROSCOPY [J].

BARTIK, T ;

BARTIK, B ;

HANSON, BE ;

GLASS, T ;

BEBOUT, W .

INORGANIC CHEMISTRY, 1992, 31 (12) :2667-2670

[3] MOLECULAR-STRUCTURES, ELECTROCHEMICAL AND SPECTROSCOPICAL PROPERTIES OF DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) AND DICHLORODICARBONYLBIS(TRIPHENYLARSINE)RUTHENIUM(II) [J].

BATISTA, AA ;

ZUKERMANSCHPECTOR, J ;

PORCU, OM ;

QUEIROZ, SL ;

ARAUJO, MP ;

OLIVA, G ;

SOUZA, DHF .

POLYHEDRON, 1994, 13 (04) :689-693

[4] A FOURIER-TRANSFORM C-13 NMR-STUDY OF THE ELECTRONIC EFFECTS OF PHOSPHORUS, ARSENIC, AND ANTIMONY LIGANDS IN TRANSITION-METAL CARBONYL-COMPLEXES [J].

BODNER, GM ;

MAY, MP ;

MCKINNEY, LE .

INORGANIC CHEMISTRY, 1980, 19 (07) :1951-1958

[5] Synthetic aspects of stereoselective hydroformylation [J].

Breit, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (04) :264-275

[6] HOMOGENEOUS HYDROFORMYLATION OF ALKENES WITH HYDRIDOCARBONYLTRIS-(TRIPHENYLPHOSPHINE)RHODIUM(I) AS CATALYST [J].

BROWN, CK ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (17) :2753-+

[7] A COMPARATIVE-STUDY OF TRIPHENYLAMINE, TRIPHENYLPHOSPHINE, TRIPHENYLARSINE, TRIPHENYLANTIMONY AND TRIPHENYLBISMUTH AS LIGANDS IN THE RHODIUM-CATALYZED HYDROFORMYLATION OF 1-DODECENE [J].

CARLOCK, JT .

TETRAHEDRON, 1984, 40 (01) :185-187

[8] Hydroformylation of alkenes employing rhodium(I) complexes and a phosphine oxide ligand [J].

Clark, HJ ;

Wang, RP ;

Alper, H .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (17) :6224-6225

[9] Arene hydrogenation in a room-temperature ionic liquid using a ruthenium cluster catalyst [J].

Dyson, PJ ;

Ellis, DJ ;

Parker, DG ;

Welton, T .

CHEMICAL COMMUNICATIONS, 1999, (01) :25-26

[10] HYDROFORMYLATION OF ALKENES BY USE OF RHODIUM COMPLEX CATALYSTS [J].

EVANS, D ;

OSBORN, JA ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (12) :3133-+

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