Dimers of Anthrathiophene and Anthradithiophene Derivatives: Synthesis and Characterization

被引：16

作者：

Balandier, Jean-Yves ^{[1
]}

Quist, Florence ^{[1
]}

Stas, Sara ^{[1
]}

Tylleman, Benoit ^{[1
]}

Ragoen, Celine ^{[1
]}

Mayence, Arnaud ^{[1
]}

Bouzakraoui, Said ^{[2
]}

Cornil, Jerome ^{[2
]}

Geerts, Yves Henri ^{[1
]}

机构：

[1] Univ Libre Bruxelles, Fac Sci, Lab Chim Polymeres, B-1050 Brussels, Belgium

[2] Univ Mons, Serv Chim Mat Nouveaux, B-7000 Mons, Belgium

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 04期

关键词：

FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; ORGANIC SEMICONDUCTORS; EXCITATION-ENERGIES; SOLUBLE PENTACENE; ACENES; APPROXIMATION; COPOLYMERS; MOLECULES; OLIGOMERS;

D O I：

10.1021/ol102776p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis, isolation, and characterization of derivatives of an anthrathiophene dimer (TOTBAT) and of anthradithiophene oligomers (ADTO), possessing octylthiophene units on their backbone, are described. These semiconductors are prepared through oxidative copper(II) chloride coupling. The spectroscopic properties and stability of these newly synthesized semiconductors were evaluated and supported by quantum-chemical calculations.

引用

页码：548 / 551

页数：4

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