Novel mixed ligand sandwich complexes:: competitive binding of iron with benzene, coronene, and C60

被引：58

作者：

Buchanan, JW ^{[1
]}

Grieves, GA ^{[1
]}

Reddic, JE ^{[1
]}

Duncan, MA ^{[1
]}

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 1999年 / 182卷

关键词：

organometallic complexes; metal ions; photodissociation;

D O I：

10.1016/S1387-3806(98)14239-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Organometallic complexes of iron with benzene, coronene and C-60 are produced in a molecular beam and studied with time-of-flight mass spectrometry and laser photodissociation. The cation complexes are produced in a pulsed nozzle laser vaporization source using an iron rod coated with a sublimed film of coronene and/or C-60. Benzene is seeded in the expansion gas. Masses of the form [A(x)-Fe-B-y](+) are observed when A and B are benzene, coronene, or C-60, taken any two at a time. Masses are observed for all combinations where x + y = 1 or 2, indicating the formation of monoligand and sandwich complexes. Mixed-Ligand sandwiches form with comparable abundance to homoligand sandwiches. Mass-selected photodissociation probes the relative bonding strengths in these new species. (C) 1999 Elsevier Science B.V.

引用

页码：323 / 333

页数：11

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[21] The cation-pi interaction [J].