Luminescence properties and crystal structures of dicyano(diimine)platinum(II) complexes controlled by Pt•••Pt and π-π interactions

被引:101
作者
Kato, M [1 ]
Kosuge, C
Morii, K
Ahn, JS
Kitagawa, H
Mitani, T
Matsushita, M
Kato, T
Yano, S
Kimura, M
机构
[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[3] Japan Adv Inst Sci & Technol, Hokuriku, Tatsunokuchi 9231292, Japan
关键词
D O I
10.1021/ic981027a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Orange-red crystals of [Pt(CN)(2)(bpy)] (bpy = 2,2' - bipyridine) and [Pt(CN)(2)(i-biq)] (i-biq = 3,3'-biisoquinoline) show completely different temperature-dependence of emission behavior which has been explained in terms of the characteristic change of each crystal structure based on the platinum-platinum and ligand pi-pi interactions.
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页码:1638 / +
页数:5
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