Synthesis and characterisation of a new high pressure polymorph of Cu2WS4

被引：33

作者：

Crossland, CJ ^{[1
]}

Evans, JSO ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 18期

关键词：

D O I：

10.1039/b306633a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this communication we report the synthesis and structural characterisation of a new body centred polymorph of Cu2WS4 prepared using hydrothermal methods. I-Cu2WS4 crystallises in space group I (4) over bar 2m with cell parameters a = b = 5.44427(8), c = 10.0687(2) Angstrom and has a new structure type containing layers of edge-sharing CuS4 and WS4 tetrahedra.

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页码：2292 / 2293

页数：2

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