Structural transformations from a 1-D chain to two 3-D supramolecular isomers via crystal disassembly and reassembly

被引:20
作者
Bai, Yue-Ling [1 ]
Tao, Jun [1 ]
Huang, Rong-Bin [1 ]
Zheng, Lan-Sun [1 ]
机构
[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
来源
CRYSTENGCOMM | 2008年 / 10卷 / 05期
关键词
D O I
10.1039/b717297d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of L(-)-malic acid (L-H(2)mal), manganese salts and triethylamine in methanol - water solution gave a 1-D chiral complex, [Mn-II(L-mal)(H2O)(CH3OH)] 2 (1), which could be rationally controlled to transform into 3-D supramolecular isomers [Mn-II(L-mal)(H2O)(2)] center dot H2O (2a and 2b, respectively).
引用
收藏
页码:472 / 474
页数:3
相关论文
共 40 条
[1]   Supramolecular isomerism in coordination compounds: Nanoscale molecular hexagons and chains [J].
Abourahma, H ;
Moulton, B ;
Kravtsov, V ;
Zaworotko, MJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (34) :9990-9991
[2]   Moisture-triggered 1,3,5-triazine-based cull molecular switch: A combined X-ray single-crystal and powder diffraction study [J].
Casellas, N ;
Gamez, P ;
Reedijk, J ;
Mutikainen, I ;
Turpeinen, U ;
Masciocchi, N ;
Galli, S ;
Sironi, A .
INORGANIC CHEMISTRY, 2005, 44 (22) :7918-7924
[3]   Solvent-dependent 44 square grid and 64.82 NbO frameworks formed by Cu(Pyac)2 (bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II)) [J].
Chen, BL ;
Fronczek, FR ;
Maverick, AW .
CHEMICAL COMMUNICATIONS, 2003, (17) :2166-2167
[4]   [Co2(ppca)2(H2O)(V4O12)0.5]:: A framework material exhibiting reversible shrinkage and expansion through a single-crystal-to-single-crystal transformation involving a change in the cobalt coordination environment [J].
Chen, CL ;
Goforth, AM ;
Smith, MD ;
Su, CY ;
zur Loye, HC .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (41) :6673-6677
[5]   Dynamic and redox active pillared bilayer open framework: Single-crystal-to-single-crystal transformations upon guest removal, guest exchange, and framework oxidation [J].
Choi, HJ ;
Suh, MP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (48) :15844-15851
[6]   A single-crystal-to-single-crystal transformation mediated by argentophilic forces converts a finite metal complex into an infinite coordination network [J].
Chu, QL ;
Swenson, DC ;
MacGillivray, LR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) :3569-3572
[7]   Syntheses, structures, and magnetic properties of three novel metal-malate-bipyridine coordination polymers with layered and pillared topology [J].
Duan, LM ;
Xie, FT ;
Chen, XY ;
Chen, Y ;
Lu, YK ;
Cheng, P ;
Xu, JQ .
CRYSTAL GROWTH & DESIGN, 2006, 6 (05) :1101-1106
[8]   Crystal engineering of NLO materials based on metal-organic coordination networks [J].
Evans, OR ;
Lin, WB .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522
[9]   Solvent-induced supramolecular isomerism in [Pt(S=C(NH2)2)4]2+ croconate salts [J].
Gale, PA ;
Light, ME ;
Quesada, R .
CHEMICAL COMMUNICATIONS, 2005, (47) :5864-5866
[10]   Supramolecular isomerism in coordination polymers: Conformational freedom of ligands in [Co(NO3)(2)(1,2-bis(4-pyridyl)ethane)(1.5)](n) [J].
Hennigar, TL ;
MacQuarrie, DC ;
Losier, P ;
Rogers, RD ;
Zaworotko, MJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (09) :972-973