Structural transformations from a 1-D chain to two 3-D supramolecular isomers via crystal disassembly and reassembly

被引:20
作者
Bai, Yue-Ling [1 ]
Tao, Jun [1 ]
Huang, Rong-Bin [1 ]
Zheng, Lan-Sun [1 ]
机构
[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
来源
CRYSTENGCOMM | 2008年 / 10卷 / 05期
关键词
D O I
10.1039/b717297d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of L(-)-malic acid (L-H(2)mal), manganese salts and triethylamine in methanol - water solution gave a 1-D chiral complex, [Mn-II(L-mal)(H2O)(CH3OH)] 2 (1), which could be rationally controlled to transform into 3-D supramolecular isomers [Mn-II(L-mal)(H2O)(2)] center dot H2O (2a and 2b, respectively).
引用
收藏
页码:472 / 474
页数:3
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