Asymmetric hydrogenation of imines catalysed by carboxylato(diphosphine)iridium(III) complexes

被引：57

作者：

Sablong, R ^{[1
]}

Osborn, JA ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST LE BEL,LAB CHIM MET TRANSIT & CATALYSE,CNRS,UNITE RECH ASSOCIEE 424,F-67070 STRASBOURG,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 11期

关键词：

D O I：

10.1016/0957-4166(96)00397-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of three new families of monomeric carboxylato(diphosphine)iridium(III) complexes is described (e.g. diphosphine = diop, binap, bdpp). Some of these complexes catalyse the asymmetric hydrogenation of prochiral imines to amines in good activity and enantioselectivity. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：3059 / 3062

页数：4

共 31 条

[1] CHIRAL SULFONATED PHOSPHINES - SYNTHESES AND USE AS LIGANDS IN ASYMMETRIC HYDROGENATION USING AN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEM
AMRANI, Y
LECOMTE, L
SINOU, D
BAKOS, J
TOTH, I
HEIL, B
[J]. ORGANOMETALLICS, 1989, 8 (02) : 542 - 547
[2] [Anonymous], COMPREHENSIVE ORGANO
[3] RHODIUM(I) SULFONATED-BDPP CATALYZED ASYMMETRIC HYDROGENATION OF IMINES IN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEMS
BAKOS, J
OROSZ, A
HEIL, B
LAGHMARI, M
LHOSTE, P
SINOU, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (23) : 1684 - 1685
[4] CATALYTIC AND STRUCTURAL STUDIES OF RHI COMPLEXES OF (-)-(2S,4S)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE - ASYMMETRIC HYDROGENATION OF ACETOPHENONEBENZYLIMINE AND ACETOPHENONE
BAKOS, J
TOTH, I
HEIL, B
SZALONTAI, G
PARKANYI, L
FULOP, V
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) : 263 - 276
[5] BEKALSKI AG, 1991, INORG CHEM, V30, P5002
[6] BOSNICH B, 1986, ASYMMETRIC CATALYSIS
[7] SELECTIVITY AND MECHANISM IN CATALYTIC ASYMMETRIC-SYNTHESIS
BROWN, JM
[J]. CHEMICAL SOCIETY REVIEWS, 1993, 22 (01) : 25 - 41
[8] ENANTIOSELECTIVE HYDROGENATION OF THE C=N GROUP - A CATALYTIC ASYMMETRIC REDUCTIVE AMINATION PROCEDURE
BURK, MJ
FEASTER, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) : 6266 - 6267
[9] CHADOSH D, 1982, INORG CHEM, V21, P1307
[10] Chan Y.-H., UNPUB

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