Measuring thermoelectric transport properties of materials

被引：296

作者：

Borup, Kasper A. ^{[1
,2
]}

de Boor, Johannes ^{[3
]}

Wang, Heng ^{[4
]}

Drymiotis, Fivos ^{[4
]}

Gascoin, Franck ^{[5
]}

Shi, Xun ^{[6
]}

Chen, Lidong ^{[6
]}

Fedorov, Mikhail I. ^{[7
,8
]}

Mueller, Eckhard ^{[9
]}

Iversena, Bo B. ^{[1
,2
]}

Snyder, G. Jeffrey ^{[4
,8
]}

机构：

[1] Aarhus Univ, Dept Chem, Ctr Mat Crystallog, DK-8000 Aarhus, Denmark

[2] Aarhus Univ, iNANO, DK-8000 Aarhus, Denmark

[3] German Aerosp Ctr, Inst Mat Res, D-51147 Cologne, Germany

[4] CALTECH, Pasadena, CA 91125 USA

[5] CNRS, ENSICAEN, Lab CRISMAT, UMR 6508, F-14050 Caen 04, France

[6] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

[7] AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia

[8] ITMO Univ, St Petersburg, Russia

[9] Univ Giessen, Inst Inorgan & Analyt Chem, D-35392 Giessen, Germany

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2015年 / 8卷 / 02期

基金：

新加坡国家研究基金会;

关键词：

INTERNATIONAL ROUND-ROBIN; 2 CANDIDATE MATERIALS; SEEBECK COEFFICIENT; THERMAL-DIFFUSIVITY; FLASH METHOD; BULK THERMOELECTRICS; HEAT-CAPACITY; PERFORMANCE; PULSE; POWER;

D O I：

10.1039/c4ee01320d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this review we discuss considerations regarding the common techniques used for measuring thermoelectric transport properties necessary for calculating the thermoelectric figure of merit, zT. Advice for improving the data quality in Seebeck coefficient, electrical resistivity, and thermal conductivity (from flash diffusivity and heat capacity) measurements are given together with methods for identifying possible erroneous data. Measurement of the Hall coefficient and calculation of the charge carrier concentration and mobility is also included due to its importance for understanding materials. It is not intended to be a complete record or comparison of all the different techniques employed in thermoelectrics. Rather, by providing an overview of common techniques and their inherent difficulties it is an aid to new researchers or students in the field. The focus is mainly on high temperature measurements but low temperature techniques are also briefly discussed.

引用

页码：423 / 435

页数：13

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