Characterization of the coordination network formed on self-assembly of 1,2-bis(3′-pyridyl)ethyne with copper(I) iodide

被引：5

作者：

Bosch, E ^{[1
]}

Cordes, W

机构：

[1] SW Missouri State Univ, Dept Chem, Springfield, MO 65804 USA

[2] Univ Arkansas, Dept Chem, Fayetteville, AR 72701 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2003年 / 33卷 / 10期

关键词：

1,2-bis(3 '-pyridyl)ethyne; copper(I) iodide; crystal structure; coordination network;

D O I：

10.1023/A:1026199105648

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The self-assembly of 1,2-bis(3'-pyridyl) ethyne with copper(I) iodide is described. The X-ray crystal structure of the resultant pale yellow crystalline solid reveals that the sheets of the two-dimensional coordination network are stacked such that channels are formed. The structure (C12H8Cu2I2N2) is monoclinic with a = 9: 285(2)Angstrom, b = 4: 1502(9) Angstrom, c = 22: 096(5)Angstrom, beta = 97: 380(11)degrees, and space group P2(1)/c.

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页码：723 / 726

页数：4

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