Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion

被引：108

作者：

Long, De-Liang ^{[1
]}

Streb, Carsten ^{[1
]}

Song, Yu-Fei ^{[1
]}

Mitchell, Scott ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 06期

关键词：

D O I：

10.1021/ja075940z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A route to unravel and the complexities of polyoxometalates in solution using electrospray mass spectrometry is presented. This reveals the limited speciation of the clusters in organic solvent compared to that in aqueous solution and allows the unambiguous assignment of the protonation states of the cluster as a function of heteroatom inclusion.

引用

页码：1830 / +

页数：4

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