Lewis acid-catalyzed Friedel-Crafts acylation reaction using carboxylic acids as acylating agents

被引:33
作者
Kawamura, M [1 ]
Cui, DM [1 ]
Hayashi, T [1 ]
Shimada, S [1 ]
机构
[1] AIST, Tsukuba, Ibaraki 3058565, Japan
关键词
Friedel-Crafts acylation; carboxylic acid; Lewis acid; rare-earth metal;
D O I
10.1016/j.tetlet.2003.08.099
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Rare-earth metal Lewis acids, in particular Eu(NTf2)(3), were found to be efficient catalysts for Friedel-Crafts acylation reaction using aliphatic as well as aromatic carboxylic acids as acylating agents at high temperature. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7715 / 7717
页数:3
相关论文
共 24 条
  • [1] FRIEDEL-CRAFTS ACYLATION OF TOLUENE AND PARA-XYLENE WITH CARBOXYLIC-ACIDS CATALYZED BY ZEOLITES
    CHICHE, B
    FINIELS, A
    GAUTHIER, C
    GENESTE, P
    GRAILLE, J
    PIOCH, D
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (11) : 2128 - 2130
  • [2] ACYLATION OVER CATION-EXCHANGED MONTMORILLONITE
    CHICHE, B
    FINIELS, A
    GAUTHIER, C
    GENESTE, P
    GRAILLE, J
    PIOCH, D
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1987, 42 (02): : 229 - 235
  • [3] Synthesis of 1-tetralones by intramolecular Friedel-Crafts reaction of 4-arylbutyric acids using Lewis acid catalysts
    Cui, DM
    Kawamura, M
    Shimada, S
    Hayashi, T
    Tanaka, M
    [J]. TETRAHEDRON LETTERS, 2003, 44 (21) : 4007 - 4010
  • [4] Heteropolyacids and large-pore zeolites as catalysts in acylation reactions using α,β-unsaturated organic acids as acylating agents
    De Castro, C
    Primo, J
    Corma, A
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 134 (1-3) : 215 - 222
  • [5] Lanthanide bis(trifluoromethylsulfonyl)amides vs. trifluoromethylsulfonates as catalysts for Friedel-Crafts acylations
    Duris, F
    Barbier-Baudry, D
    Dormond, A
    Desmurs, JR
    Bernard, JM
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 188 (1-2) : 97 - 104
  • [6] INFLUENCE OF ACIDITY IN FRIEDEL-CRAFTS ACYLATION CATALYZED BY ZEOLITES
    GAUTHIER, C
    CHICHE, B
    FINIELS, A
    GENESTE, P
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1989, 50 (02): : 219 - 229
  • [7] Ishihara K, 1996, SYNLETT, P265
  • [8] ACIDIC ALKALI-METAL SALTS AND AMMONIUM-SALTS OF KEGGIN TYPE HETEROPOLYACIDS AS EFFICIENT SOLID ACID CATALYSTS FOR LIQUID-PHASE FRIEDEL-CRAFTS REACTIONS
    IZUMI, Y
    OGAWA, M
    NOHARA, W
    URABE, K
    [J]. CHEMISTRY LETTERS, 1992, (10) : 1987 - 1990
  • [9] Efficient acylation of toluene and anisole with aliphatic carboxylic acids catalysed by heteropoly salt Cs2.5H0.5PW12O40
    Kaur, J
    Kozhevnikov, IV
    [J]. CHEMICAL COMMUNICATIONS, 2002, (21) : 2508 - 2509
  • [10] Friedel-Crafts reactions catalyzed by rare earth metal trifluoromethanesulfonates
    Kawada, A
    Mitamura, S
    Matsuo, J
    Tsuchiya, T
    Kobayashi, S
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (10) : 2325 - 2333