Long lifetime photoluminescence emission of 3D cadmium metal-organic frameworks based on the 5-(4-pyridyl)tetrazole ligand

被引：18

作者：

Calahorro, Antonio J. ^{[1
]}

Salinas-Castillo, Alfonso ^{[2
]}

Fairen-Jimenez, David ^{[3
]}

Seco, Jose M. ^{[4
]}

Mendicute-Fierro, Claudio ^{[4
]}

Gomez-Ruiz, Santiago ^{[5
]}

Lopez-Viseras, Marta E. ^{[1
]}

Rodriguez-Dieguez, Antonio ^{[1
]}

机构：

[1] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

[2] Univ Granada, Dept Quim Analit, E-18071 Granada, Spain

[3] Univ Cambridge, Dept Chem Engn & Biotechnol, Cambridge CB2 1TN, England

[4] Univ Basque Country, Fac Ciencias Quim San Sebastian, Dept Quim Aplicada, San Sebastian 20018, Spain

[5] Univ Rey Juan Carlos, Dept Quim Inorgan & Analit, Madrid, Spain

来源：

INORGANICA CHIMICA ACTA | 2015年 / 427卷

关键词：

MOF; Hydrothermal; Cadmium; Luminescence; Adsorption; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; LUMINESCENCE PROPERTIES; MAGNETIC-PROPERTIES; METHANE STORAGE; H-2; ADSORPTION; CARBON-DIOXIDE; GAS-STORAGE; COMPLEXES; ZINC;

D O I：

10.1016/j.ica.2014.12.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new metal-organic frameworks based on 5-(4-pyridyl) tetrazole have been synthesized by hydrothermal routes mixing this linker with cadmium(II) chloride in the presence of secondary ligands such as squaric acid, 4-carboxypyridine and terephthalic acid in water. Hydrothermal syntheses reveal new possibilities to rational formation on MOFs by mixtures of different linkers using the appropriate stoichiometry. These polymers exhibit blue-green photoluminescence emission at room temperature in the solid state with long lifetime decays. Theoretical studies about pore size distribution and experimental gas adsorption studies have also been included. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：131 / 137

页数：7

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