Nanosilicon-Coated Graphene Granules as Anodes for Li-Ion Batteries

被引:235
作者
Evanoff, Kara [1 ]
Magasinski, Alexandre [1 ]
Yang, Junbing [2 ]
Yushin, Gleb [1 ]
机构
[1] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA
[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA
关键词
LITHIUM INSERTION; COMPOSITE ANODES; CARBONACEOUS MATERIALS; RAMAN-SPECTROSCOPY; SILICON; PERFORMANCE; STORAGE; ELECTRODES; GRAPHITE; INSERTION/EXTRACTION;
D O I
10.1002/aenm.201100071
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Uniform deposition of Si and C layers on high surface area graphene produces granules with specific surface area of ∼5 m 2· g -1. The anode composed of the nanocomposite particles exhibited specific capacity in excess of 2000 mAh·g -1 at a current density of 140 mA·g -1 and excellent stability for 150 cycles. The low surface area of the composite resulted in an average Cou-lombic efficiency in excess of 99%. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:495 / 498
页数:4
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