Synthesis and structure of a triptycene-based nanosized molecular cage

被引：109

作者：

Zhang, Chun ^{[1
]}

Chen, Chuan-Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Ctr Chem Biol, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 24期

关键词：

D O I：

10.1021/jo7017526

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[Graphics] A triptycene-based nanosized molecular cage was designed and efficiently synthesized by Eglington-Glaser coupling reaction, and its structure was determined by NMR, MS spectrometry and X-ray analysis. Moreover, it was found that the cage molecules could pack into a microporous structure in the solid state and 1,3,5-trimethylbenzene molecules were located in the channels.

引用

页码：9339 / 9341

页数：3

共 49 条

[1] Polyethynylated cyclic π-systems:: scaffoldings for novel two and three-dimensional carbon networks [J].

Bunz, UHF ;

Rubin, Y ;

Tobe, Y .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (02) :107-119

[2] Self-assembling capsules [J].

Conn, MM ;

Rebek, J .

CHEMICAL REVIEWS, 1997, 97 (05) :1647-1668

[3] The big squeeze:: Guest exchange in an M4L6 supramolecular host [J].

Davis, AV ;

Raymond, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (21) :7912-7919

[4]

Diederich F., 2004, ACETYLENE CHEM

[5]

DIEDERICH F, 1995, MODERN ACETYLENE CHE, P443

[6] Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels [J].

Fiedler, D ;

Leung, DH ;

Bergman, RG ;

Raymond, KN .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :349-358

[7] Coordination assemblies from a Pd(II)-cornered square complex [J].

Fujita, M ;

Tominaga, M ;

Hori, A ;

Therrien, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378

[8]

Grave C, 2002, EUR J ORG CHEM, V2002, P3075

[9]

Haley MM, 1999, TOP CURR CHEM, V201, P81

[10] Pairwise selection of guests in a cylindrical molecular capsule of nanometre dimensions [J].

Heinz, T ;

Rudkevich, DM ;

Rebek, J .

NATURE, 1998, 394 (6695) :764-766

← 1 2 3 4 5 →