Green Catalysts Derived from Agricultural and Industrial Waste Products: The Preparation of Phenols from CsOH and Aryl Iodides using CuO on Mesoporous Silica

被引：31

作者：

Chan, Chien-Ching ^{[2
]}

Chen, Yan-Wun ^{[1
]}

Su, Chi-Shen ^{[1
]}

Lin, Hong-Ping ^{[1
]}

Lee, Chin-Fa ^{[2
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 701, Taiwan

[2] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 36期

关键词：

Supported catalysis; Meso-porous materials; Waste prevention; Sustainable chemistry; Copper; Cross-coupling; RICE HUSK ASH; COPPER-CATALYSTS; HYDROXYLATION; HALIDES; DEHYDROGENATION; ETHANOL; ETHERS;

D O I：

10.1002/ejoc.201101206

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of CuO catalysts supported on mesoporous silica derived from rice husks and semiconductor copper from chemical mechanical planarization (Cu-CMP) wastewater is described. These catalysts are active for the coupling reaction of CsOH with aryl iodides. Low catalyst loading (1 mol-%) without the need for ancillary ligands make these very attractive green catalysts.

引用

页码：7288 / 7293

页数：6

共 39 条

[1]

Adam F., 2006, J. Phys. Sci, V17, P1, DOI DOI 10.1016/S1872-2067(12)60751-7

[2] Oxidation of benzene over bimetallic Cu-Ce incorporated rice husk silica catalysts [J].

Adam, Farook ;

Thankappan, Radhika .

CHEMICAL ENGINEERING JOURNAL, 2010, 160 (01) :249-258

[3] Transition-Metal-Catalyzed Synthesis of Hydroxylated Arenes [J].

Alonso, Diego A. ;

Najera, Carmen ;

Pastor, Isidro M. ;

Yus, Miguel .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (18) :5274-5284

[4] The selective reaction of aryl halides with KOH: Synthesis of phenols, aromatic ethers, and benzofurans [J].

Anderson, Kevin W. ;

Ikawa, Takashi ;

Tundel, Rachel E. ;

Buchwald, Stephen L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (33) :10694-10695

[5] Oxidation of aromatic aldehydes and ketones by H2O2/CH3ReO3 in ionic liquids:: a catalytic efficient reaction to achieve dihydric phenols [J].

Bernini, R ;

Coratti, A ;

Provenzano, G ;

Fabrizi, G ;

Tofani, D .

TETRAHEDRON, 2005, 61 (07) :1821-1825

[6] Ethanol dehydrogenation over copper catalysts on rice husk ash prepared by ion exchange [J].

Chang, FW ;

Yang, HC ;

Roselin, LS ;

Kuo, WY .

APPLIED CATALYSIS A-GENERAL, 2006, 304 (01) :30-39

[7] Preparation of Cr2O3-promoted copper catalysts on rice husk ash by incipient wetness impregnation [J].

Chang, FW ;

Kuo, WY ;

Yang, HC .

APPLIED CATALYSIS A-GENERAL, 2005, 288 (1-2) :53-61

[8] Dehydrogenation of ethanol over copper catalysts on rice husk ash prepared by incipient wetness impregnation [J].

Chang, FW ;

Kuo, WY ;

Lee, KC .

APPLIED CATALYSIS A-GENERAL, 2003, 246 (02) :253-264

[9] Synthesis of CuO on mesoporous silica and its applications for coupling reactions of thiols with aryl iodides [J].

Chen, Chin-Keng ;

Chen, Yan-Wun ;

Lin, Che-Hung ;

Lin, Hong-Ping ;

Lee, Chin-Fa .

CHEMICAL COMMUNICATIONS, 2010, 46 (02) :282-284

[10] Palladium-catalyzed C-O bond formation: direct synthesis of phenols and aryl/alkyl ethers from activated aryl halides [J].

Chen, Guoshu ;

Chan, Albert S. C. ;

Kwong, Fuk Yee .

TETRAHEDRON LETTERS, 2007, 48 (03) :473-476

← 1 2 3 4 →