Synthesis of dimeric iminoalanes by oxidative addition of azides to (CpAl)(4): Structural characterization of (CpAlNSi(t)Bu(3))(2) (Cp*=C(5)Me(5))

被引：55

作者：

Schulz, S ^{[1
]}

Voigt, A ^{[1
]}

Roesky, HW ^{[1
]}

Haming, L ^{[1
]}

HerbstIrmer, R ^{[1
]}

机构：

[1] UNIV GOTTINGEN, INST ANORGAN CHEM, D-37077 GOTTINGEN, GERMANY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 24期

关键词：

D O I：

10.1021/om960138j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (Cp*Al)(4) with organic azides offers an alternative synthetic route for the formation of iminoalanes with a low degree of oligomerization. This method was used to prepare the dimeric iminoalanes (Cp*(AlNSiPr3)-Pr-i)(2) (1), (Cp*AlNSiPh(3))(2) (2), and (Cp*AlNSi(t)Bu(3))(2) (3). The crystal structure of 3 was determined by X-ray diffraction study.

引用

页码：5252 / 5253

页数：2

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Synthesis of dimeric iminoalanes by oxidative addition of azides to (Cp*Al)(4): Structural characterization of (Cp*AlNSi(t)Bu(3))(2) (Cp*=C(5)Me(5))

Synthesis of dimeric iminoalanes by oxidative addition of azides to (CpAl)(4): Structural characterization of (CpAlNSi(t)Bu(3))(2) (Cp*=C(5)Me(5))