Electrochemical deposition under oxidizing conditions (EDOC): A new synthesis for nanocrystalline metal oxides

被引：79

作者：

Dierstein, A

Natter, H

Meyer, F

Stephan, HO

Kropf, C

Hempelmann, R

机构：

[1] Univ Saarlandes, D-66123 Saarbrucken, Germany

[2] Henkel KGAA, D-40191 Dusseldorf, Germany

来源：

SCRIPTA MATERIALIA | 2001年 / 44卷 / 8-9期

关键词：

elctrochemical preparation; metal oxides; nanocrystalline; crystal growth;

D O I：

10.1016/S1359-6462(01)00906-X

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

EDOC (Electrochemical Deposition under Oxidizing Conditions) is a new method for the electrochemical preparation of metal oxide nanoparticles. It is based on the reduction of metal ions; Coming from a sacrificial anode; In a non-aqueous medium. The formed metal clusters are immediately coated with stabilizers; Which prevent the particles from agglomeration and realize the nanocrystalline state. Thus we have prepared numerous amorphous and crystalline metal oxides; Mixed oxides and oxide mixtures (ZnO; Mn3O4, CuO; Fe2O3, SnO2, In2O3, ZrO2, NiO; Co3O4, CoFe2O4, In2O3/SnO2 etc.) in the nanometre range with narrow particle size distribution (sigma = 1.15-1.4). (C) 2001 Acta Materialia Inc. Published by Elsevier Science Ltd. All rights reserved.

引用

页码：2209 / 2212

页数：4

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