Hole and Electron Extraction Layers Based on Graphene Oxide Derivatives for High-Performance Bulk Heterojunction Solar Cells

被引:283
作者
Liu, Jun [1 ]
Xue, Yuhua [1 ,2 ]
Gao, Yunxiang [1 ]
Yu, Dingshan [1 ]
Durstock, Michael [3 ]
Dai, Liming [1 ]
机构
[1] Case Western Reserve Univ, Case Sch Engn, Dept Macromol Sci & Engn, Ctr Adv Sci & Engn Carbon Case4Carbon, Cleveland, OH 44106 USA
[2] Wenzhou Med Coll, Sch Ophthalmol & Optometry, Inst Adv Mat Nanobio Applicat, Zhejiang 325027, Peoples R China
[3] USAF, Res Lab, RXBP, Mat & Mfg Directorate, Wright Patterson AFB, OH 45433 USA
基金
美国国家科学基金会;
关键词
bulk heterojunction solar cells; graphene oxides; charge extraction; cesium; functionalization; POLYMER PHOTOVOLTAIC CELLS; CARBON; DONOR; FILMS;
D O I
10.1002/adma.201104945
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By charge neutralization of carboxylic acid groups in graphene oxide (GO) with Cs 2CO 3 to afford Cesium-neutralized GO (GO-Cs), GO derivatives with appropriate modification are used as both hole- and electron-extraction layers for bulk heterojunction (BHJ) solar cells. The normal and inverted devices based on GO hole- and GO-Cs electron-extraction layers both outperform the corresponding standard BHJ solar cells. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2228 / 2233
页数:6
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